Magnetism in Gemstones
An Effective Tool and Method for Gem Identification
© Kirk Feral 2012, All Rights Reserved. These materials may be duplicated for educational purposes only. No part of this website may be duplicated or distributed for profit, for commercial purposes, or for posting to another website, without the expressed written consent of the copyright holder.
Nearly 60% of all HPHT synthetic Diamonds tested in our published study (Gems & Gemology journal, Winter 2012) could be detected with a magnetic wand, either by the Direct method or Floatation method. This suggests that jewelers and diamond dealers can use the Direct method to quickly scan a parcel of loose natural Diamonds with a magnet to detect synthetics. Study results found that 85% of HPHT synthetics over a half carat in weight were magnetically detectable. Although rare, most synthetic Diamonds over 1 carat are yellow HPHT synthetics, and all such examples in our study contained enough flux metal to show a Pick-up response to a magnet.
HPHT Synthetic Diamonds
Published literature by this author and others cite how magnetic response can often distinguish synthetic Diamonds from natural Diamonds of any color. It is not the dopants used in synthetics that cause magnetic attraction. The dopants used are the same elements found in color centers in natural colored Diamonds: boron for blue color and nitrogen for yellow color. These elements are non-metals, and they are not magnetic. Irradiation (natural or laboratory) can induce pink color, as well as blue color in natural and synthetic Diamonds. Both natural and synthetic Diamonds often fluoresce under UV light, but fluorescence in synthetics is often brighter and more garish in color.
The magnetic attraction we often see in colorless and colored synthetic Diamonds manufactured under high pressure and high temperature (HPHT) is due to ferromagnetic inclusions of iron and nickel flux that are present as remnants of the manufacturing process. Often these gems will be picked up by a magnet. Any magnetic attraction at all, weak or strong, indicates a synthetic Diamond containing metallic particles. Both the Direct method and Floatation method can be used to identify synthetic Diamonds. Becasue the inclusions are ferromagnetic, a tiny Pinpoint wand works equally well as our standard 1/2" wand. Synthetic HPHT Diamonds are the only transparent gemstones that show ferromagnetic responses to a hand-held magnet, in contrast to the paramagnetic and diamagnetic responses we normally encounter.
Not all synthetic Diamonds are created by the HPHT process. Newer on the market are CVD synthetic Diamonds, which are manufactured by a different process called Chemical Vapor Deposition. This process deposits carbon without involving metallic flux. All CVD synthetic Diamonds, regardless of color, are magnetically inert (diamagnetic) and cannot be separated from natural Diamonds by magnetic response. This type of synthetic Diamond is encountered less frequently in jewelry than HPHT Diamond, but that could change over time.
Direct Method: A Colorless HPHT Synthetic Diamond Picks Up
Natural Diamond is Inert
GGG Picks Up
Pink CZ (Drag Response)
Synthetic Diamonds: Manufactured Diamonds (not imitations) are now making their way into the jewelry market. These are made entirely of elemental carbon, as are natural Diamonds. They are currently expensive to manufacture. Natural and synthetic Diamonds can look identical to the naked eye, and often can be difficult to differentiate using standard testing methods. A Diamond tester cannot distinguish natural Diamond from synthetic Diamond.
Colorless CVD & Yellow HPHT
All These Pink HPHT
Synthetic Diamonds Pick Up
Floatation Method: A Yellow HPHT Synthetic
Diamond Shows a Strong Response
Diamonds: Natural, Imitation & Synthetic
Natural Diamonds are magnetically inert (diamagnetic). They can be imitated by natural Zircon, and by many man-made materials such as Moissanite, Strontium Titanate and synthetic Rutile (all diamagnetic). Gadolinium Gallium Garnet (GGG), Yttrium Aluminum Garnet (YAG) and Cubic Zirconia (CZ) are man-made imitations that can show magnetic attraction. By far the most common Diamond imitation used today is CZ. More recently, lab-created synthetic Diamonds made entirely from carbon are also being produced.
Natural Diamonds: Most natural Diamonds are colorless, but they are also found in a variety of colors. Yellow, pink and blue are the most common. These colors can occur naturally in Diamond, but they are rare. Most of the colored Diamonds we find on the market have been treated with irradiation, high heat, high pressure or a combination of processes to create color. None of these treatments affect the magnetic response of natural Diamond, which is, with rare exception, inert (diamagnetic) regardless of color.
Yellow CZ (Moderately Magnetic)
Colored CZ and YAG often give themselves away as imitation Diamonds by their magnetic attraction. These lab gems can imitate yellow, pink and blue Diamond rather well, as shown in the photos below. The Yellow CZ depicted below (left) shows a moderate magnetic response due to the rare earth dopant neodymium. The yellow YAG (right) is doped with the manganese (Mn2+) and shows no magnetic attraction.
Natural Treated Diamonds of All Colors Are Inert
Not all yellow CZ's are magnetic. Magnetic response in any of these imitations varies with the types and concentrations of dopants (coloring agents) used during production. Dopants can be transition metals or rare earth metals. Fortunately, rare earth dopants often produce absorption spectra that can be clearly seen with a handheld spectroscope. Such pronounced spectra are not seen in natural Diamonds.
Pictured below are CZ and YAG gems imitating pink Diamond. The bright pink CZ shows a Drag response due to the rare earth dopants erbium and holmium. The pale pink YAG is similarly doped and also shows a Drag response, but the Drag response is much weaker due to lower concentrations of the dopants. The dark pink YAG trillion on the right shows a Pick Up response and has a density that is as high as that of CZ (5.7) due to an unusually high concentration of erbium (as verified by JTV's lab analysis).
Yellow YAG (Inert)
Blue CZ (Inert)
Blue YAG (Weakly Magnetic)
Magnetic testing with a Pinpoint wand can be useful for identifying small individual HPHT synthetic Diamonds in cluster jewelry, and for detecting jewelry imitations like GGG, pink and yellow CZ, and pink and blue YAG that show magnetic attraction. An electronic Diamond-and-Moissanite tester is the simplest way to determine if each individual gem in such jewelry is genuine Diamond or an imitation. But the electronic tester fails to distinguish between man-made Diamonds and natural Diamonds. In such cases, a Pinpoint wand comes in handy. Any magnetic attraction to the Pinpoint wand indicates the Diamond is man-made.
Pinpoint Testing for Synthetic Diamonds Containing Metallic Inclusions
The blue CZ shown below (left) appears to be colored by cobalt and iron in low concentration. It is inert (diamagnetic). The blue YAG on the right is colored by neodymium in low concentration. It is weakly magnetic. Any magnetic attraction encountered in transparent gems during testing eliminates natural Diamond as a possibility.
Pink YAG (Drag Response)
Pink YAG (Drag Response)
For a more detailed look at magnetism in Diamonds, see our feature article "Detecting HPHT Synthetic Diamonds Using a Handheld Magnet" in the Winter 2012 issue of Gems and Gemology.
This concludes our discussion of magnetism in Diamonds. To learn about magnetism in Sapphire and Ruby, go to the Sapphire and Ruby section.
Untreated Colorless Diamond (Inert)
Unfortunately, not all HPHT synthetic Diamonds contain detectable metallic inclusions, and this is particulary true for very small gems. Not all can be separated from natural Diamonds with a magnet. About half of HPHT synthetics under a half carat show no attraction to a neodymium magnet even when the Floatation method is used.
Visible Black Metallic Inclusions in
Yellow HPHT Synthetic Diamond
CZ and YAG: These imitations can be colorless, and colorless examples are indistinguishable by magnetic response from genuine colorless Diamonds. All are inert. Like Diamond, these colorless imitations are singly refractive and have refractive indices that are too high to be measured with a standard refractometer. To spot a colorless imitation, we can measure density (specific gravity) or use an electronic Diamond tester.
When colorless, all diamond imitations are inert (diamagnetic), with the notable exception of GGG, which picks up as a result of strong paramagnetism. The pick-up response of colorless GGG (and colored GGG) quickly identifies it. No other colorless gems, except some synthetic Diamonds, show such a magnetic response (due to ferromagnetism). Other than GGG, magnetic testing cannot be used to distinguish natural colorless Diamonds from colorless imitations.