Magnetism in GemstonesAn Effective Tool and Method for Gem Identification
Garnets are some of the most magnetic gemstones, and magnetic testing gives us rare insights into the world of Garnets, revealing how the different species and varieties of Garnet are related. For most people, the term Garnet brings to mind a dark red gem, but Garnets are in fact a diverse group of gemstones, with more species and color varieties than any other type of transparent gemstone.
There are 15 species of Garnet recognized by mineralogists, but most are of little interest to gemologists. Only 6 Garnet species produce gem-quality crystals that are fashioned into gemstones. These are Almandine, Pyrope, Spessartine, Grossular, Andradite and Uvarovite. Almandine, a red to purplish red gem, is the most common species. Gem-quality Uvarovite is only found as clusters of tiny green crystals (druse), and Uvarovite jewelry is fashioned from druse slabs.
Grossular Garnet Cubic Crystal from Canada
Blue Color Change Garnet
In addition to red, Garnets are found in every color, from colorless to black, pink, purple, blue, green, orange, yellow, and even iridescent. Some Garnets change color from daylight to incandescent light, much like Alexandrite. There are also hundreds of more subtle color variations among gem-grade Garnets. Some varieties have only been discovered in the last few decades, and some are among the world's rarest gemstones. We'll take a tour of all of them, and present a considerable amount of new information about Garnets never before published.
© Kirk Feral 2011, All Rights Reserved. These materials may be duplicated for educational purposes only. No part of this website may be duplicated or distributed for profit, for commercial purposes, or for posting to another website without the expressed written consent of the copyright holder.
The World of Garnets
What are Garnets?
The Garnet group falls within the family of Orthosilicate minerals, all with related chemical compositions. Other Orthosilicates include Peridot, Zircon, Topaz, Andalusite, and many secondary gems such as Kyanite and Sphene. What all these gemstones share in common is the chemical component SiO4 (one silicon atom per 4 oxygen atoms) in their chemical formulas. The generic formula for Garnet is:
Garnets belong to the cubic crystal system, and therefore gems are isotropic (singly refractive). However, under a polariscope, anomalous double refraction is common in red and green Garnets due to distortion of the isotropic cubic crystal structure during metamorphic conditions of high pressure and high temperature. Garnets are found all over the world. Some of the most unusual gem varieties come from African countries such as Namibia, Tanzania and Madagascar. Garnets are one of the few primary gems that are generally not treated, although Demantoid, and occasionally Hessonite (Bear Wiliams, pers. comm., 2011), are known to be heated to enhance color. The synthetic Garnet GGG is no longer manufactured for gem purposes, and synthetic Garnet YAG is found only in limited quantities.
The extreme diversity seen in Garnets is the result of different species mixing together in endless variation. We'll see how magnetic testing can reveal exactly how different Garnet species have blended within an individual gem. Based on analysis of over 500 Garnets, we present a new proposed Gem Garnet Classification system, as well as the first Graph of All Gem Garnets showing composition ranges for all known gem Garnets.
Rhodolite Garnet from Burma
Hessonite Garnet from Nigeria
Garnets are Found in Many Colors
© Kirk Feral
Why So Many Varieties?
Garnets species are separated into different varieites based on variations in color. To learn why there is such tremendous color variation in Garnets, it’s helpful to have a basic understanding of the chemical formula shown below. The letters A and B simply represent sites where ions of specificchemical elements can bond with silicon and oxygen to give a Garnet a chemical composition unique to its particular species.
The A and B sites can be partially filled by calcium, magnesium or aluminumions, none of which cause color. But coloring agents can also occupy these sites. The four principal metals that can cause color in Garnets by occupying sites A or B are iron (purplish red, brown, yellow), manganese (orange, pink), chromium (red, green), and vanadium (green). Combinations of these chromophores in varying concentrations result in a bewildering variety of color and subtle variations in hue. Charge transfer processes may also play a role in creating and modifying color. When chromium is present, Garnets with low iron content (Grossular Garnets and Pyrope-Spessartine Garnets) also fluoresce pink or red under long wave UV light.
Pure End Member SpeciesChemical formulas for the six species of gem Garnet are shown below. Chromophores are highlighted in color, with the valence number added in superscript for clarification. These formulas represent the chemistry of pure Garnet species, also referred to as end-members. Chromophores (color-producing metal ions) are found at the A site in Pyralspite Garnet species, and at the B site in Ugrandite Garnet species.
The 100% pure end-member Garnets shown above don't exist in nature. As you can see, pure Pyrope Garnet would be colorless, as there are no transition metal chromophores in the A or B sites, only magnesium and aluminum. The graph point for pure Pyrope would plot at zero magnetic susceptibility. Pure colorless gem Pyrope is not known, but rare near-colorless gems do exist. The most familiar Pyrope gems are red and significantly magnetic due to mixing with other Garnet species such as Uvarovite/Knorringite (chromium) and Almandine (iron).
Pure Grossular Garnet would also be colorless and diamagnetic because there are no chromophores in the A and B sites, only calcium and aluminum. In this case, Grossular gems do approach the pure end-member in composition, and examples of pure colorless gems do exist. These are called Leuco Garnets, though in most cases these Garnets retain a hint of color and a measurable amount of magnetism.
Near-colorless Grossular Garnets:
Hessonite, Green Grossular, Mali
Contents of this Section
Pg 1) The World of Garnets
Orange Spessartine Garnet