Magnetism in Gemstones
An Effective Tool for Gem Identification
© Kirk Feral
Black, Orange, Blue, Green
Black: This is the most common color of Tourmaline found in nature, but black Tourmalines are seldom faceted as gemstones. Most belong to the Schorl species, which is an opaque Tourmaline that is often black in color. Schorl owes its color and lack of transparency to high concentrations of 3 transition metals: 1) iron within its chemical formula, 2) manganese impurities, and 3) titanium impurities. Titanium contributes color through inter-valence charge transfer (Fe2+-Ti4+). Charge transfer processes involving other ions also contribute to the black color. Black Tourmalines show a Drag response. Quantitative measurements of magnetic susceptibility tell us that opaque black Tourmalines are by far the most magnetic of all the color varieties of gem Tourmaline.
Black Tourmalines
(2.42ct. & 2.23ct., Drag, SI 990 &1150)
Tourmaline species are classified according to chemical compositions that are often unrelated to color or magnetism. Different species generally can’t be distinguished from one another by their color or magnetic responses or magnetic susceptibility measurements. Gems of different species can have the same color, and the transition metal impurities and charge transfer processes that appear in one species may also appear in other species. For example, not all black Tourmalines are Schorl. Some Dravite and Uvite gems are also black. Another example is brown and orange Tourmaline.
Brown and Orange: Dravite is typically a brown or orangey brown Tourmaline colored by iron to titanium charge transfer (Fe2+-Ti4+). The iron is derived from mixing with Schorl. Iron ions in brown Tourmalines are often not magnetically detectable because only very low concentrations of iron are needed to create color through the iron-titanium (Fe2+-Ti4+) charge transfer process.
The 3 brown Tourmalines pictured below show an Inert (Diamagnetic) response to an N52 magnet. Their color and lack of magnetic attraction are not specific to the Dravite species alone. Elbaite, Liddicoatite and Uvite gems can also be brown, presumably due to the same iron-titanium charge transfer process. Some of the brown Tourmalines in our study have been identified by Raman spectroscopy as Elbaite. However, for the sake of simplicity we will assume that most brown Tourmalines shown below are Dravite.
These Brown Tourmalines are Diamagnetic
"Chrome" Tourmalines and "Verdelite" Tourmalines can sometimes look alike (see comparison below left). Pale green or mint green "Chrome" Tourmalines with light colors due to lower concentrations of vanadium and chromium can look identical to pale green Tourmalines colored by iron (see the oval and rectangle gems below right). Fortunately, we can use magnetic response to easily separate these Tourmalines whether they are light green or dark green.
"Chrome" Tourmalines (Dravite species) of any color intensity usually show an Inert (Diamagnetic) response, or in some cases very weak attraction. Only 2 of 11 "Chrome" Tourmalines tested in our study show slight magnetic attraction. In contrast, green Elbaite Tourmalines of any color intensity caused by iron (Fe2+) show significant magnetic attraction, either via the Direct Method or Floatation Method.
"Chrome" Tourmaline (.86ct., Inert, SI <0) & "Verdelite" (.79ct., Drag, SI 317)
Blue: Most blue Tourmalines (Elbaite species) are colored by ferrous iron (Fe2+) as well as iron to iron charge transfer (Fe2+ - Fe3+). The iron is derived from mixing with Schorl in solid solution series. On rare occasions, Tourmalines are formed in a geologic environment that is high in copper. The copper will contribute blue color in such Tourmalines, which have been given the trade name "Paraiba" Tourmalines (see page 3).
Magnetic response can identify blue "Indicolite" Tourmaline, which is a Tourmaline with indogo blue, pure blue blue or blue-green color. Most Indicolites belong to the Elbaite species, but Raman spectroscopy identifies the oval gem below (right) as Liddicoatite. "Inidicolite" is colored by iron, and a Drag response is diagnostic for this variety. This is the only blue gemstone of any kind, not just Tourmaline, that will show a Drag response.
Often blue and green colors mix within a single Tourmaline gem. Strictly speaking, only pure indigo blue gems such as the oval gem above (right) are "Indicolite", but pure blue gems are seldom seen. Most dark blue gems referred to as "Indicolite" contain some amount of green, like the gem shown above left. The square gem pictured in the photo below left seems to have equal amounts of blue and green color. It shows a Drag response, but can we call it "Indicolite"? The bi-color oval in the photo below right is predominantly dark blue, but it also has some green and yellow color. It shows only a Moderate response, indicating much lower iron content than what we see in "Indicolite". These are just two of many examples of Tourmalines in shades and mixtures of colors that do not neatly fit any single color variety or trade name.
Greenish Blue Tourmaline
(2.59ct., Drag, SI 304)
Blue & Green Tourmaline
(2.85ct., Moderate, SI 91)
Our study of Tourmaline magnetism uncovered other surprising results. As an example, not all dark blue Tourmalines show a Drag response typical of "Indicolite". The gem pictured below (left) shows only a Weak response when floated, and the gem on the right shows only a Strong response. We can speculate that the dark blue color in the gem on the left may be primarily influenced by inter-valence charge transfer between iron ions (Fe2+-Fe3+), while dark blue color in the gem on the right may be controlled more by the concentration of iron (Fe2+) ions.
Dark Blue Tourmalines
(.92ct., Weak, SI 69 & .911ct., Strong, SI 218)
Green: Green is the most common color of transparent gem Tourmaline. Color ranges from "grass" green to bluish green to "Emerald" green, and color intensity can range from very light to very dark. Green "Verdelite" Tourmaline is colored by dispersed ions of iron (Fe2+, derived from mixing with Schorl) in conjunction with iron-titanium (Fe2+ - Ti4+) charge transfer.
Pale Green (4.1ct., Moderate, SI 69) &
"Verdelite" (4.1ct., Drag, SI 278)
Pale Green (1.15ct., Moderate, SI 117) &
"Verdelite" (.79ct., Drag, SI 317)
Grayish green and blackish green Tourmalines are fairly common. Below are 3 examples. The over-dark green hexagon on the left shows a combination of green and gray colors. The color may be influenced by natural radiation. Studies have shown that lab irradiation of some green Tourmalines can produce gray color (Kurt Nassuau, 1975). This may involve alteration of the valence state of iron from Fe2+ (green) to Fe3+ (gray), as well as to Fe2+-Ti4+ charge transfer.
The magnetic response of the hexagonal gem (left) is Weak. The blackish green trillion in the center shows a Strong magnetic response. These 2 Tourmalines have magnetic susceptibilities that correspond to pale green gems. In fact, if the black component could be removed, these Tourmalines might show only pale green color.
Blackish Green Tourmaline
(5.36 ct., Weak, SI 74)
© Kirk Feral 2013, All Rights Reserved. These materials may be duplicated for educational purposes only. No part of this website may be duplicated or distributed for profit, for commercial purposes, or for posting to another website without the expressed written consent of the copyright holder.
Blue-green "Indicolite"
(5.25ct., Drag, SI 447)
"Chrome" Tourmaline (1.58ct., Inert, SI <0) &
Pale Green Tourmaline (1.15ct., Moderate, SI 117)
9.2ct.
Pale Green (5.06, Weak, <20 SI) &
"Verdelite" (5.94ct., Drag, SI 360)
When a handheld spectroscope is applied to the gems above, we see no definitive absorption spectra that might help us separate the 2 species of green Tourmaline. A Chelsea filter (and sometimes a UV light) is another definitive tool that can help us identify "Chrome" Tourmalines, as these gems often show a red or pink reaction. Vanadium usually quenches red chromium fluorescence in dark green "Chrome" Tourmalines.
But Tourmalines colored by vanadium will show neither a Chelsea filter reaction nor UV fluorescence. In these cases, a handheld magnet is the most definitive tool we have to separate green Dravite Tourmaline from green Elbaite.
One “Chrome” Tourmaline with an unusual brownish green or "olive" green color was also encountered in our study, as pictured below. This diamagnetic gem shows pink/red fluorescence from chromium under long wave UV light. Chromium/vanadium is confirmed with a spectrometer as the primary cause of color. The cause of the brownish secondary hue has not been determined, but it is most likely due to trace amounts of iron or titanium.
Paler blue colors and shades colored by iron are also found among Tourmalnes. Pale gems that are greenish blue and powder blue can be appropriately referred to as blue Tourmalines rather than as "Indicolite". The magnetic susceptibility of these blue Tourmalines corresponds to the intensity of color. The two gem triads pictured below show a progression of increasing color saturation from near-colorless to dark blue. Magnetic susceptibility (SI) of the gems in each triad also progressively increases from left to right.
Much of the dark blue portion on the left side of this bi-color gem is opaque, except at the facet edges where it is thin and transparent. This blue portion shows a Drag response. It also shows color change (dichromatism). When viewed in intensely bright incandescent transmitted light, the opaque dark blue color becomes transparent lavender (reddish light + blue body color = lavender). Opaque black Schorl has also been reported to appear lavender when cut in thin section. Surprisingly, the colorless portion on the right side of this gem retains enough iron (Fe3+) to show weak to moderate magnetic attraction, indicating the iron is cryptic.
Blue Becomes Lavender in
Transmitted Incandescent Light
Moderate Drag Drag
Weak Strong Drag
Indigo Blue "Indicolite"
(.41ct., Drag, SI 382)
Blackish Green Tourmaline Rough
(17.62ct., Strong, SI 286)
Tourmalines:
The blackish brown Tourmaline round from Sri Lanka pictured below (left) appears opaque and black in reflected light and can easily be mistaken for black Schorl. Transmitted light (back lighting) reveals that this gem is actually transparent and dark brown. The gem shows a Moderate magnetic response, and we can speculate that this may be due to "surplus" iron that is not engaged in iron-titanium charge transfer. Perhaps for the same reason, the translucent brown rough Tourmaline on the right shows a Weak magnetic response. The magnetism could also be partly due to manganese (Mn2+).
Opaque Black in Reflected Light &
Transparent Brown in Transmitted Light
The 2 brown gems shown below are both strongly magnetic. The oval gem on the left also has yellow and green color, while the pear-shaped gem on the right is yellowish brown. The yellow color in these gems is likely due to manganese, whose presence is suggested by spectrometer analysis. Manganese as Mn2+ can impart strong magnetic susceptibility, as we will show in several other color varieties of Tourmaline.
(1.32ct., Moderate, SI 78)
Yellowish Greenish Brown
(6.65ct., Strong, SI 265)
Yellowish Brown
(2.41ct., Strong, SI 221)
Orange is often a component color of brown Tourmalines. On rare occasions, pure orange gems are also found, as depicted by the 2 gems below. Like brown Tourmaline colored by iron and Fe2+-Ti4+ charge transfer, these orange Tourmalines show no attraction to a magnet.
Orange Tourmaline
(1.1ct., Diamagnetic, SI < 0)
The pinkish-brownish-orange Tourmaline pear pictured below (left) also shows no magnetic attraction, as we would expect. The square Tourmaline on the right has similar color, but it shows a Drag response. In fact, it is the most magnetic transparent Tourmaline tested in this study. How is this possible? The causes of color for this gem cannot be definitively determined with a spectrometer, but we can guess that manganese is primarily responsible for the exceptionally strong magnetism. Manganese can contribute to the magnetic susceptibility of Tourmalines of any color without necessarily contributing to color.
Pinkish Brownish Orange
(2.1ct., Drags, SI 547)
2.9ct.
Pinkish Brownish Orange
(.62ct., Diamagnetic, SI <0)
Orange Tourmaline
(.75ct., Diamagnetic, SI < 0)
(7.75ct., Weak)
Bluish green color is more often seen in Tourmalines of the Elbaite species. In these instances, color appears to be due to a mixture of iron Fe2+ ions (blue) and iron to titanium (Fe2+-Ti4+) charge transfer (green). Below are 2 examples. The trillion on the left is only moderately magnetic, while the shield on the right shows a Drag response. The difference in magnetic susceptibilities of these 2 gems of similar color is due to a higher concentration of iron in the gem on the right.
Bluish Green
(3.65ct. Moderate, SI 65)
Bluish Green
(1.6ct, Drags, SI 382)
Blackish Green Tourmaline
(2.69 ct., Strong, SI 130)
In green Tourmalines colored by iron, there is a correlation between color intensity and magnetic susceptibility, just as there is with blue Tourmalines colored by iron. Light green gems show much weaker magnetic responses than dark green "Verdelite" gems (see 3 examples below). We can assume that light green gems are Weak to Moderate due to relatively low iron content, while dark green gems show either a Strong response or a Drag response due to high iron content.
"Verdelite" Tourmaline
(19.46ct., Strong, SI 295)
Note: Besides helping us to identify or separate gems, a magnetic wand provides a means to quickly and efficiently flag gems with unexpected magnetic properties, such as the blue Tourmalines above. We can isolate these gems as candidates for further analysis in order to uncover what is different about them in terms of causes of color.
Black Tourmaline Rough Crystals 17mm
The rough Tourmaline crystal shown above (right) appears opaque black in reflected light and could easily be mistaken for Schorl. But in transmitted light the rough appears translucent blackish-green. It is the most magnetic of the three Tourmalines above, but still not strong enough to show a Drag response characteristic of dark green "Verdelite" gems and opaque black Schorl. The primary species composition of this crystal could be Elbaite, Dravite or Uvite.
Brown Tourmaline Rough Crystal
Cryptic Iron: Iron (Fe3+) is a weak chromophore, and lower concentrations of Fe3+ may not produce color in some gems. These Fe3+ ions can appear invisible or cryptic, as we see in the colorless end of this Indicolite Tourmaline. Such cryptic iron also does not absorb enough light to show detectable absorption lines under a spectroscope, but the iron can be detected with more sensitive instruments such as a spectrometer or a magnetic wand. The spectrometer graph below clearly shows the presence of Fe3+ in completely colorless Tourmaline.
Iron (Fe3+) in a Completely Colorless Section of Tourmaline
Increasing Concentration of Iron in 3 Dark Blue Tourmalines
Spectrometer analysis comparing the 2 gems above to an "Indicolite" gem supports our hypothesis. The graph below shows that the gem above right has a higher iron content than the gem above left, and that both have a lower concentration of iron than "Indicolite" Tourmaline, which shows a drag response.
We can compare relative magnetic susceptibilities of green Tourmalines to blue Tourmalines by referring to the bar graph near the top of this page. The graph shows that pale green gems are on average less magnetic than pale blue gems. Dark green "Verdelite" and dark blue "Indicolite" are equally magnetic.
Brownish Green "Chrome" Tourmaline
Daylight and UV Fluorescence
(0.17ct, Inert, SI <0)
Chrome Tourmaline belongs to the Dravite speceis, and is a much rarer type of green Tourmaline than green Elbaite. These Dravites typically show dark green color. They are colored by vanadium ions (V3+) derived from mixing with the idiochromatic Vanadium-Dravite species, and also by chromium ions (Cr3+) derived from mixing with the idiochromatic Chromium-Dravite species.
Although these dark green Tourmalines are referred to as "Chrome" Tourmalines, chemical analyses have shown that vanadium is usually the primary cause of color. However some Dravite Tourmalines may actually contain a higher concentration of chromium than vanadium, and these can more legitimately be considered Chrome Tourmalines.
Because of the low concentrations of chromium/vanadium in transparent "Chrome" Tourmaline, the primary species composition of most gems is Dravite (or in rare cases Uvite) rather than Chromium-Dravite or Vanadium-Dravite. "Chrome" Tourmalines are mostly iron-free and diamagnetic, but some are faintly attracted to a magnet due to a combined magnetic susceptibility of chromium, vanadium and iron.
The Chrome Tourmaline shown below has a rich green color typical of the variety, and it is diamagnetic. It is glows red under a Chelsea filter, and also fluoresces red under long wave UV light due to chromium. Most "Chrome" Tourmalines do not fluoresce under UV light, but when a tourmaline does fluoresce like the one below, it may be an indication that the gem is colored primarily by chromium rather than vanadium. Chrome Tourmaline is the only variety of Tourmaline that can fluoresce red under long wave UV light.
"Chrome" Tourmaline (1.02ct., Inert, SI <0)
Daylight and UV Fluorescence
"Verdelite" Tourmaline
(1.02ct., Drag, SI 295)
"Chrome" Tourmaline (1.57ct, Inert, SI <0)
Most dark green "Chrome" Tourmalines sold in the marketplace are actually "Vanadium" Tourmalines, deriving more of their color from vanadium than from chromium. But the the trade name Chrome Tourmaline has been established, and that's not likely to change.
Lower concentrations of vanadium and chromium result in lighter green colors. The two unusual green Tourmalines shown below were sold as "Chrome" Tourmalines, although neither one shows typical "chrome green" color. The reaction under a Chelsea filter is very faint pink, and there is no LWUV fluorescence, indicating that the light green color is due primarily to low concentrations of vanadium rather than chromium.
Although both of these gems are colored primarily by small amounts of vanadium, Chelsea filter and fluorescent reactions suggests that the light green gem on the right has a somewhat higher ratio of vanadium to chromium than the moderate green gem on the left. Neither gem contains any magnetically detectable iron, and the vanadium/chromium content is also magnetically undetectable. These "Chrome" Tourmalines are both diamagnetic, and both fluoresce a weak yellow color under short wave UV light, possibly due to vanadium.
"Chrome" Tourmaline (14.10ct, Inert, SI >0)
The color of the 3.23ct bi-color Indicolite Tourmaline pictured below changes from opaque dark blue on the left side to colorless on the right side. The refractive index of this gems starts high at 1.63-1.655 on the dark blue end and decreases to the typical Elbaite range of 1.62-1.64 on the colorless end. These unusual changes within a single gem are due to variations in iron content. Lower concentrations of iron (blue color) result in lower densities along the length of the gem, accompanied by lower refractive indices.
Progressive changes in magnetism can also be measured within this same bi-color gem. Measurements taken at 8 different points along the length of the 24mm bar show a ten-fold decrease in magnetic susceptibility from SI 781 to SI 78 due to progressively lower iron content. It is probable that the dark blue portion with susceptibilities above 500 is primarily Schorl (a separate species) rather than "Indicolite" (Elbaite species).
Bi-color Indicolite Tourmaline
Bi-color Indicolite Tourmaline
With a Chelsea filter, UV flashlight and spectrometer, we have determined that the dark green "Chrome" Tourmaline pictured below is more typical and colored primarily by vanadium. No chromium absorption peak at 680nm is visible with a spectrometer. Unlike chromium, vanadium does not cause red UV fluorescence in gemstones. The gem below shows no chromium fluorescence under long wave UV light, but it does show a strong red reaction under the Chelsea filter. This indicates that chromium is indeed present. But any UV fluorescence from chromium is quenched by vanadium. The quenching is not due to iron, as the gem is diamagnetic and contains only a trace amount of iron.
"Chrome" Tourmaline
Colored Primarily by Vanadium
Vanadium-dravite is an idiochromatic species of tourmaline that is colored by a high concentration of vanadium. Unlike “Chrome” Tourmaline of the dravite species, Vanadium-dravite contains little or no chromium and does not appear red under a Chelsea filter. Although it's seldom of gem quality, we encountered a rare example of a faceted Vanadium-dravite that was bluish green in color and strongly magnetic due to vanadium.
Vanadium-dravite Tourmaline
(2.53ct., Strong, SI 213)
Pure Blue "Indicolite"
(3.53ct., Drag, SI 356)